Nuclear Chemistry Vocabulary

Activation energy (Ea) – The minimum amount of energy required for a reaction to occur.

Alpha(a) particle – A particle ejected in one form of radioactive decay, identical to the helium-4 nucleus.  A common mode of decay for radioactive nuclides in which the mass number changes.

Atomic mass – The averaged mass of the atoms of an element, taking into account the relative abundance of the various isotopes in a naturally occurring substance.  Also called the atomic weight which is recorded on the Periodic Table.

Atomic mass units (amu) – A unit of mass defined as 1/12 the mass of a carbon-12 atom; approximately equal to the mass of one proton or one neutron.

Atomic number (Z) – The number of protons in a given element, atom or isotope.

Becquerel (Bq)  - A measure that enables us to compare the typical radioactivity of some natural and other materials. A becquerel is one atomic decay per second.

Beta (b) - An electron produced and ejected during radioactive beta decay.

Beta (b) production – A decay process for radioactive nuclides in which the mass number remains constant and atomic number changes.  The net effect is to change a neutron to a proton.

Binding energy – The energy required to break a nucleus apart (decompose) into its constituent neutrons and protons.

Carbon-14 (radiocarbon) dating – A technique for estimating the age of (ancient) objects by measuring the amount of radioactive carbon-14 remaining.  A second definition states it is based on the rate of radioactive decay of the nuclide  .

Cyclotron- A type of particle accelerator in which an ion introduced at the center is accelerated in an expanding spiral path by the use of alternating electrical fields in the presence of a magnetic field.

Fission – The process of using a neutron to split a heavy nucleus into two nuclei with small mass numbers.

Fusion – The process of combining two light nuclei to form a heavier, more stable nucleus.

Gamma (g) decay – releases energy but does not change A or Z.

Gamma (g) radiation – High energy photons often emitted in radioactive decay. 

Geiger counter (Geiger-Műller counter) - An instrument used to measure radioactivity or the rate of radioactive decay based on the ions and electrons produced as a radioactive particle passes through a gas-filled chamber.

Half-life – The time required for the amount of a reactant to decrease to one-half of its former value.

Isotope – Atoms of the same element (the same number of protons) with different number of neutrons.  They have identical atomic numbers (Z) but differ in mass numbers (A).

Isotopic Symbol – A short hand symbol of an isotope specifying the mass number (A), atomic number (Z) and element symbol (X)  in the form .

Mass defect – The difference between the sum of the masses of neutrons and protons forming a nucleus and the mass of that nucleus; the mass equivalence of binding energy, with the two related via the equation E=mc2.   Note: the mass of a nucleus is always less than the combined masses of its constituent protons and neutrons.

Mass number (A) ­ - The sum of the protons and neutrons of an atom or isotope.

Neutron (N) – A subatomic particle contained within the nucleus of an atom.  It carries no charge and has a mass very slightly larger than that of a proton.

Nucleon – A particle found in the nucleus of an atom; can be either a neutron or a proton.

Nucleus – The small central region of an atom; a dense, positively charged area containing protons and neutrons.

Nuclide- The general term applied to each unique atom; represented by  where X is the symbol for a particular element.

Particle accelerator- A device used to accelerate nuclear particles to very high speeds.

Photon- A quantum of energy in the form of light with a value of Planck’s constant multiplied by the frequency of the light.  (E=hn)

Positron – An “anti-electron”:  It has the same mass but opposite charge as an electron, and is emitted during a particular form of radioactive decay.

Proton  – A subatomic particle that carries a single positive charge and has a mass defined as one .  The number of protons in an element, atom or isotope is equal to the Atomic Number (Z).

Rad – A unit of radiation dosage corresponding to 10-2 J of energy deposited per kilogram of tissue (from radiation absorbed dose).

Radioactive Decay Half-Life (T1/2) – The fraction of original nuclei remaining after n half-lives = (½)n.  The fraction of nuclei that has decayed away after n  half-lives = 1 - (½)n.

Radioactivity- A phenomenon exhibited by certain unstable isotopes in which they undergo spontaneous nuclear transformations via emission of one or more particles.

Radiotracer (aka Tracer) – A tracer is a radioactive nuclide, introduced into an organism for diagnostic purposes, whose pathway can be “traced” by monitoring its radioactivity.

Reactor core – The part of a nuclear reactor where the fission reaction takes place.

Rem – A unit of radiation dosage that accounts for both the energy of the dose and its effectiveness in causing biological damage (from roentgen equivalent for man).

Scintillation counter – An instrument used to measure radioactivity by sensing the flashes of light produced in a substance by the radiation (the amount of fluorescence produced).

Spontaneous process – A process that will occur on its own without energy input from the surroundings.

Z – Represents the number of protons and is equivalent to the atomic number.

Zone of nuclear stability – The area encompassing the stable nuclides on a plot of their positions as a function of the number of protons and the number of neutrons in the nucleus.

A particular combination of protons and neutrons is called a nuclide. Nuclides with the same number of protons are called isotopes. Nuclides with the same mass number are isobars. Nuclides with the same number of neutrons are isotones.